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1 article(s) from Mihailciuc, Constantin

Synthesis and properties of fluorescent 4′-azulenyl-functionalized 2,2′:6′,2″-terpyridines

Adrian E. Ion,
Liliana Cristian,
Mariana Voicescu,
Masroor Bangesh,
Augustin M. Madalan,
Daniela Bala,
Constantin Mihailciuc and
Simona Nica

Beilstein J. Org. Chem. 2016, 12, 1812–1825, doi:10.3762/bjoc.12.171

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Scheme 1: Synthesis of 4′-azulenyl substituted terpyridines.

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Figure 1: Molecular structure and numbering scheme of 4′-(1-azulenyl)-2,2′:6′,2″-terpyridine (4a, left) and 4...

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Figure 2: Packing diagram for 4a showing the π–π stacking and CH–π interactions between the pyridine rings an...

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Figure 3: Packing diagram for 4b showing the π–π stacking between the pyridine rings. Hydrogen atoms are omit...

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Figure 4: Absorption spectra of the azulene-containing terpyridine, 4a and 4b in CH₂Cl₂ solution at room temp...

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Figure 5: Emission spectra of the azulene-containing terpyridine, 4a and 4b in CH₂Cl₂ solution (2.59 × 10⁻⁵ M...

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Figure 6: Selected Kohn–Sham orbitals and orbital energies for 4a and 4b, obtained with three different funct...

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Figure 7: DPV-traces (with baseline correction) of 0.5 mM solutions of 4a (solid) and 4b (dash) in DMF, with ...

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Figure 8: Absorption spectra of a 4.26 mM solution of 4a in methanol upon titration with an aqueous HgCl₂ sol...

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Figure 9: Absorption spectra of a 4.26 mM solution of 4a in methanol upon titration with CdCl₂ aqueous soluti...

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Published 11 Aug 2016

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